Bifunctional supramolecular systems on the platform of p-sulfonatothiacalix[4]arene containing photochromic mononitrosyl Ru (II) and paramagnetic aqua Gd or Dy complexes

Two bifunctional supramolecular systems [RuNO(NH sub(3)) sub(4)OH] super(2+) super(.)[RuNO(NH sub(3)) sub(4)H sub(2O]) super(3)+ super(.Gd) super( )3+(H sub(2O)) sub(6) super(.2[TCAS]) super(4)- super(.4H) sub(2)O (1) and [RuNO(NH sub(3)) sub(4)OH] super(2+) super(.)[RuNO(NH sub(3)) sub(4)H sub(2O])...

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Published in:Physica. B, Condensed matter Condensed matter, 2010-06, Vol.405 (11S), p.S30-S33
Main Authors: KUSHCH, L. A, YAGUBSKII, E. B, WOIKE, Th, DMITRIEV, A. I, MORGUNOV, R. B, EMEL'YANOV, V. A, MUSTAFINA, A. R, GUBAIDULLIN, A. T, BURILOV, V. A, SOLOVIEVA, S. E, SCHANIEL, D
Format: Article
Language:English
Subjects:
Cations
Condensed matter
Crystal structure
Dysprosium
Infrared radiation
Platforms
Rare earth metals
SQUIDs
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Summary:Two bifunctional supramolecular systems [RuNO(NH sub(3)) sub(4)OH] super(2+) super(.)[RuNO(NH sub(3)) sub(4)H sub(2O]) super(3)+ super(.Gd) super( )3+(H sub(2O)) sub(6) super(.2[TCAS]) super(4)- super(.4H) sub(2)O (1) and [RuNO(NH sub(3)) sub(4)OH] super(2+) super(.)[RuNO(NH sub(3)) sub(4)H sub(2O]) super(3)+ super(.Dy) super( )3+(H sub(2O)) sub(6) super(.2[TCAS]) super(4)- super(.4H) sub(2)O (2) on the platform of p-sulfonatothiacalix[4]arene containing photochromic mononitrosyl Ru and paramagnetic rare-earth (Gd super(3+, Dy) super(3)+) cations have been synthesized. The crystal structures of 1 and 2 are discussed. Their photochromic, magnetic and photomagnetic properties studied by IR and SQUID experimental techniques are presented
ISSN:0921-4526
1873-2135
DOI:10.1016/j.physb.2009.11.065