Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules

We report a strategy to synthesize materials in which POMs are enclosed in the cages of ZIFs. In three new compounds, H sub(3)PW sub(12)O sub(40) is a subset of ZIF-8 (BIT-1), H sub(4)SiW sub(12)O sub(40 ) is a subset of ZIF-8 (BIT-2) and H sub(3)PMo sub(12)O sub(40 ) is a subset of ZIF-8 (BIT-3), d...

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Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2014-01, Vol.2 (7), p.2168-2173
Main Authors: Li, Rui, Ren, Xiaoqian, Zhao, Jingshu, Feng, Xiao, Jiang, Xin, Fan, Xinxin, Lin, Zhengguo, Li, Xingguo, Hu, Changwen, Wang, Bo
Format: Article
Language:English
Subjects:
Acetal resins
Cages
Controlled release
Materials selection
Polyoxometallates
Strategy
Sustainability
Uptakes
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cited_by cdi_FETCH-LOGICAL-c400t-bc25845f11cfdaabb62f1523b0387b450cd8dab78b0a252323bc53d4943a8af63
cites cdi_FETCH-LOGICAL-c400t-bc25845f11cfdaabb62f1523b0387b450cd8dab78b0a252323bc53d4943a8af63
container_end_page 2173
container_issue 7
container_start_page 2168
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 2
creator Li, Rui
Ren, Xiaoqian
Zhao, Jingshu
Feng, Xiao
Jiang, Xin
Fan, Xinxin
Lin, Zhengguo
Li, Xingguo
Hu, Changwen
Wang, Bo
description We report a strategy to synthesize materials in which POMs are enclosed in the cages of ZIFs. In three new compounds, H sub(3)PW sub(12)O sub(40) is a subset of ZIF-8 (BIT-1), H sub(4)SiW sub(12)O sub(40 ) is a subset of ZIF-8 (BIT-2) and H sub(3)PMo sub(12)O sub(40 ) is a subset of ZIF-8 (BIT-3), different POM cages are 'trapped' inside the well-defined cages of ZIF-8 by one-pot mechanochemical synthesis. They show the highest capacity for methylene blue and controlled release of the anti-cancer agent 5-fluorouracil. BITs can be fully recovered and reused without losing their uptake capacity.
doi_str_mv 10.1039/c3ta14267a
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source Royal Society of Chemistry Journals
subjects Acetal resins
Cages
Controlled release
Materials selection
Polyoxometallates
Strategy
Sustainability
Uptakes
title Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules
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