Microwave assisted synthesis of MnO2 on nickel foam-graphene for electrochemical capacitor

• Published in: Electrochimica acta 2013-12, Vol.114, p.48-53
• Main Authors: Bello, A., Fashedemi, O.O., Fabiane, M., Lekitima, J.N., Ozoemena, K.I., Manyala, N.
• Format: Article
• Language: English
• Subjects: Chemical vapor deposition; CVD; Electrochemical capacitor; Graphene; Microwave irradiation; Microwaves; Nanostructure MnO2; Nickel; Nickel foam-graphene (NF-G); Raman spectroscopy; Scanning electron microscopy; Synthesis; Three dimensional
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2013.09.134

•Three-dimensional synthesis of graphene using CVD.•Hydrothermal deposition (microwave irradiation) of MnO2 on graphene.•Morphologies of the composite reveals flower-like nanostructures of MnO2 on graphene.•Composite exhibit excellent electrochemical performance. A green chemistry approach (hydrothermal microwave irradiation) has been used to deposit manganese oxide on nickel foam-graphene. The 3D graphene was synthesized using nickel foam template by chemical vapor deposition (CVD) technique. Raman spectroscopy, X-ray diffraction (XRD), scanning electron and transmission electron microscopies (SEM and TEM) have been used to characterize structure and surface morphology of the composite, respectively. The Raman spectroscopy measurements on the samples reveal that 3D graphene consists of mostly few layers with low defect density. The composite was tested in a three electrode configuration for electrochemical capacitor, and exhibited a specific capacitance of 305Fg−1 at a current density of 1Ag−1 and showed excellent cycling stability. The obtained results demonstrate that microwave irradiation technique could be a promising approach to synthesis graphene based functional materials for electrochemical applications.