Thermal characterization of the oxo-degradation of polypropylene containing a pro-oxidant/pro-degradant additive

• Published in: Polymer degradation and stability 2013-11, Vol.98 (11), p.2117-2124
• Main Author: Contat-Rodrigo, L.
• Format: Article
• Language: English
• Subjects: Additives; Ageing; Aging; Applied sciences; biodegradation; Compounding ingredients; crystal structure; Degradation; Differential scanning calorimetry; Differential scanning calorimetry (DSC); Exact sciences and technology; melting point; Miscellaneous; monitoring; Oxidation; Photo-oxidation; photooxidation; Physical properties; Polymer industry, paints, wood; Polypropylene (PP); Polypropylenes; Pro-oxidant/pro-degradant additive; Properties and testing; soil; Soil biodegradation; soil microorganisms; Technology of polymers; temperature; thermal degradation; Thermal properties; Thermogravimetric analysis (TGA); thermogravimetry; Ultraviolet radiation
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2013.09.011

The oxo-degradation process of polypropylene (PP) samples containing different concentrations (4% and 10% w/w) of pro-oxidant/pro-degradant additive Envirocare™ AG1000C was investigated under accelerated test conditions. Samples were initially exposed to UV radiation for 300 h. The tendency to biodegradation in soil medium of these UV-aged samples was then indirectly assessed by an indirect method for a period of 6 months. The entire degradation process of these materials was first examined by monitoring changes in their morphological properties (melting temperature, maximum lamellar thickness and crystallinity) with the ageing time, by Differential Scanning Calorimetry (DSC). Then, changes in the thermal properties (onset temperature and maximum decomposition temperature) of these materials with the ageing time were analysed by Thermogravimetric Analysis (TGA). Furthermore, the kinetics of the thermal decomposition of these PP samples with pro-oxidant/pro-degradant was also studied during the oxo-degradation process, by means of the Chang differential method. During exposure to UV radiation, the more significant changes in the morphological and thermal properties that were detected in PP samples containing pro-oxidant/pro-degradant additive compared to pure PP, clearly suggest a higher level of oxidation in these samples, confirming the effectiveness of this pro-oxidant/pro-degradant additive in promoting the abiotic oxidation of polypropylene during UV-irradiation. Moreover, the level of oxidation observed in UV-aged samples seems to be dependent on the additive load. On the other hand, during incubation in soil medium, changes in the morphological and thermal properties of previously photo-oxidized PP samples with pro-oxidant/pro-degradant were detected that indirectly support a certain progress of oxidation, indicating that previous abiotic oxidation can promote further degradation of the polypropylene matrix by soil microorganisms. In general, both morphological and thermal properties exhibit a non-linear dependency with the incubation time in soil, supporting the idea that biodegradation is a complex process that occurs in different stages. Furthermore, the extent of the changes in these properties during soil incubation was found to be proportional to the pro-oxidant/pro-degradant load and the previous photo-oxidation level.