Simple process for production of hydroxymethylfurfural from raw biomasses of girasol and potato tubers

• Published in: Biomass & bioenergy 2012-04, Vol.39, p.484-488
• Main Authors: Yi, Young-Byung, Lee, Jin-Woo, Choi, Young-Hun, Park, Suk-Man, Chung, Chung-Han
• Format: Article
• Language: English
• Subjects: acetates; Alternative fuels. Production and utilization; Applied sciences; Biofuel production; Biological and medical sciences; Biomass; Biotechnology; Catalysts; Chemical industry and chemicals; Chlorides; Chromium; Chromium chloride; Energy; Exact sciences and technology; Extraction; Extraction time; Fuels; Fundamental and applied biological sciences. Psychology; Girasol tuber; Hydrochloric acid; Hydroxymethylfurfural; Industrial applications and implications. Economical aspects; Industrial chemicals; ionic liquids; Miscellaneous; Organic industry; Potato tuber; potatoes; Raw; Reaction time; Solanum tuberosum; starch; tubers
• ISSN: 0961-9534; 1873-2909
• DOI: 10.1016/j.biombioe.2012.01.011

A simple production process of hydroxymethylfurfural (HMF) was developed by examining its reaction conditions in an ionic liquid, 3-methylimidazolium chloride ([OMIM]Cl). For this, effects of five parameters; extraction time, reaction time, HCl concentration, chromium dichloride (CrCl2) catalyst, and raw plant biomass sources (girasol as a source of inulin and potato tubers as a source of starch); on the yield of HMF were scrutinized. The results showed that HMF yield was significantly affected by each parameter or their combination. The best extraction time and reaction time were identified at 2h and 60min, respectively. HCl concentration optima were determined at 0.3M for girasol biomass and 0.5M for potato tuber. The presence of CrCl2 in the reaction mixture prepared from potato tuber biomass exhibited approximately a 2-fold increase in the yield of HMF (54.4%±5.1% dwt). In contrast, in girasol reaction mixture, its catalytic effect was not detected. The highest HMF yield (58.2±5.8% dwt) was achieved in the reaction mixture of 4g [OMIM]Cl, 1ml ethyl acetate, and 5ml girasol extract (prepared at 2h extraction in 0.3M HCl) without CrCl2 catalyst by undergoing the reaction at 120°C for 60min. ► We demonstrated girasol is an excellent biomass for production of HMF. ► The catalytic effect of CrCl2 on the synthesis of HMF was not found in girasol. ► Addition of CrCl2 increased by ca. 2-fold in HMF yield in potato biomass. ► Higher HMF yield was obtained in girasol than in potato biomass. ► The highest HMF yield (58.2% dwt) was obtained in girasol biomass.