The Construction of a Novel Bromido- and Azido-Bridged Dinuclear Copper(II) Complex Derived From 4-Chloro-2-[(2-hydroxyethylimino)methyl]phenol

A novel bromido- and azido-bridged dinuclear copper(II) complex, [Cu 2 Br 2 L 2 ]·[Cu 2 Br(N 3 )L 2 ]·H 2 O, where L is the deprotonated form of the Schiff base 4-chloro-2-[(2-hydroxyethylimino)methyl]phenol, has been prepared and structurally characterized by elemental analysis, IR spectra, and sin...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2013-07, Vol.43 (6), p.687-690
Main Authors: Qian, Shao-Song, Li, Hai-Hua, Cheng, Xiao-Shan, You, Zhong-Lu, Zhu, Hai-Liang
Format: Article
Language:English
Subjects:
Bridging
COMPOSITES
Construction
Copper
copper complex
COPPER COMPOUNDS
crystal structure
dinuclear complex
LIGANDS
MICROSTRUCTURES
Nanocomposites
Nanostructure
Schiff base
Schiff bases
SINGLE CRYSTALS
Spectra
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Summary:A novel bromido- and azido-bridged dinuclear copper(II) complex, [Cu 2 Br 2 L 2 ]·[Cu 2 Br(N 3 )L 2 ]·H 2 O, where L is the deprotonated form of the Schiff base 4-chloro-2-[(2-hydroxyethylimino)methyl]phenol, has been prepared and structurally characterized by elemental analysis, IR spectra, and single crystal X-ray crystallography. Each Cu atom in the complex is coordinated by three donor atoms of Schiff base ligand and by two bridging atoms, forming a square pyramidal geometry. The bromide and azide ligands are preferred bridging groups for the construction of dinuclear copper complexes with Schiff bases.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2012.753623