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Hydrogen sorption properties of MgH2/NaBH4 composites
The hydrogen sorption properties of magnesium hydride–sodium borohydride composites prepared by means of high-energy ball milling under Ar atmosphere were investigated. Mutual influence of milling time and the content of NaBH4 were studied. Microstructural and morphological analyses were carried out...
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| Published in: | International journal of hydrogen energy 2013-09, Vol.38 (27), p.12140-12145 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c375t-8de01a588d87bc9dfc0deacdf31f0fb5eac5565ebeaf229720765ed69dbb55e43 |
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| cites | cdi_FETCH-LOGICAL-c375t-8de01a588d87bc9dfc0deacdf31f0fb5eac5565ebeaf229720765ed69dbb55e43 |
| container_end_page | 12145 |
| container_issue | 27 |
| container_start_page | 12140 |
| container_title | International journal of hydrogen energy |
| container_volume | 38 |
| creator | Kurko, Sandra Aurora, Annalisa Gattia, Daniele Mirabile Contini, Vittoria Montone, Amelia Rašković-Lovre, Željka Novaković, Jasmina Grbović |
| description | The hydrogen sorption properties of magnesium hydride–sodium borohydride composites prepared by means of high-energy ball milling under Ar atmosphere were investigated. Mutual influence of milling time and the content of NaBH4 were studied. Microstructural and morphological analyses were carried out using X-ray Diffraction (XRD), laser scattering measurements and Scanning Electron Microscopy (SEM), while kinetic analysis and cycling were performed in a Sievert's volumetric apparatus. It has been shown that low content of NaBH4 and short milling time are beneficial for hydrogen sorption kinetics.
•Ball milling with NaBH4 significantly improves MgH2 hydrogen sorption kinetics.•Composite has very good hydrogen cycling properties.•Concentration of catalyst and milling time are important for kinetics improvement. |
| doi_str_mv | 10.1016/j.ijhydene.2013.04.075 |
| format | article |
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•Ball milling with NaBH4 significantly improves MgH2 hydrogen sorption kinetics.•Composite has very good hydrogen cycling properties.•Concentration of catalyst and milling time are important for kinetics improvement.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2013.04.075</identifier><identifier>CODEN: IJHEDX</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alternative fuels. Production and utilization ; Applied sciences ; Ball milling ; Diffraction ; Energy ; Exact sciences and technology ; Fuels ; Hydrogen ; Hydrogen storage ; Hydrogen-based energy ; Kinetics ; Lasers ; Magnesium ; MgH2/NaBH4 composites ; Scanning electron microscopy ; Sorption ; Sorption cycling</subject><ispartof>International journal of hydrogen energy, 2013-09, Vol.38 (27), p.12140-12145</ispartof><rights>2013 Hydrogen Energy Publications, LLC.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c375t-8de01a588d87bc9dfc0deacdf31f0fb5eac5565ebeaf229720765ed69dbb55e43</citedby><cites>FETCH-LOGICAL-c375t-8de01a588d87bc9dfc0deacdf31f0fb5eac5565ebeaf229720765ed69dbb55e43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27683329$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kurko, Sandra</creatorcontrib><creatorcontrib>Aurora, Annalisa</creatorcontrib><creatorcontrib>Gattia, Daniele Mirabile</creatorcontrib><creatorcontrib>Contini, Vittoria</creatorcontrib><creatorcontrib>Montone, Amelia</creatorcontrib><creatorcontrib>Rašković-Lovre, Željka</creatorcontrib><creatorcontrib>Novaković, Jasmina Grbović</creatorcontrib><title>Hydrogen sorption properties of MgH2/NaBH4 composites</title><title>International journal of hydrogen energy</title><description>The hydrogen sorption properties of magnesium hydride–sodium borohydride composites prepared by means of high-energy ball milling under Ar atmosphere were investigated. Mutual influence of milling time and the content of NaBH4 were studied. Microstructural and morphological analyses were carried out using X-ray Diffraction (XRD), laser scattering measurements and Scanning Electron Microscopy (SEM), while kinetic analysis and cycling were performed in a Sievert's volumetric apparatus. It has been shown that low content of NaBH4 and short milling time are beneficial for hydrogen sorption kinetics.
•Ball milling with NaBH4 significantly improves MgH2 hydrogen sorption kinetics.•Composite has very good hydrogen cycling properties.•Concentration of catalyst and milling time are important for kinetics improvement.</description><subject>Alternative fuels. Production and utilization</subject><subject>Applied sciences</subject><subject>Ball milling</subject><subject>Diffraction</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fuels</subject><subject>Hydrogen</subject><subject>Hydrogen storage</subject><subject>Hydrogen-based energy</subject><subject>Kinetics</subject><subject>Lasers</subject><subject>Magnesium</subject><subject>MgH2/NaBH4 composites</subject><subject>Scanning electron microscopy</subject><subject>Sorption</subject><subject>Sorption cycling</subject><issn>0360-3199</issn><issn>1879-3487</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkM1OwzAQhC0EEqXwCigXJC5J7Ti2kxs_AoJU4AJny7HXxVEaBztF6tuTqoUrp92VvtnZHYQuCc4IJnzRZq793BroIcsxoRkuMizYEZqRUlQpLUpxjGaYcpxSUlWn6CzGFmMicFHNEKu3JvgV9En0YRid75Mh-AHC6CAm3iYvqzpfvKq7uki0Xw8-uhHiOTqxqotwcahz9PH48H5fp8u3p-f722WqqWBjWhrARLGyNKVodGWsxgaUNpYSi23Dpp4xzqABZfO8EjkW02R4ZZqGMSjoHF3v9043fW0gjnLtooauUz34TZSEC8IE4TmfUL5HdfAxBrByCG6twlYSLHc5yVb-5iR3OUlcyCmnSXh18FBRq84G1WsX_9S54CWleTVxN3sOpoe_HQQZtYNeg3EB9CiNd_9Z_QBdjIIG</recordid><startdate>20130910</startdate><enddate>20130910</enddate><creator>Kurko, Sandra</creator><creator>Aurora, Annalisa</creator><creator>Gattia, Daniele Mirabile</creator><creator>Contini, Vittoria</creator><creator>Montone, Amelia</creator><creator>Rašković-Lovre, Željka</creator><creator>Novaković, Jasmina Grbović</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SP</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130910</creationdate><title>Hydrogen sorption properties of MgH2/NaBH4 composites</title><author>Kurko, Sandra ; Aurora, Annalisa ; Gattia, Daniele Mirabile ; Contini, Vittoria ; Montone, Amelia ; Rašković-Lovre, Željka ; Novaković, Jasmina Grbović</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c375t-8de01a588d87bc9dfc0deacdf31f0fb5eac5565ebeaf229720765ed69dbb55e43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Alternative fuels. Production and utilization</topic><topic>Applied sciences</topic><topic>Ball milling</topic><topic>Diffraction</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fuels</topic><topic>Hydrogen</topic><topic>Hydrogen storage</topic><topic>Hydrogen-based energy</topic><topic>Kinetics</topic><topic>Lasers</topic><topic>Magnesium</topic><topic>MgH2/NaBH4 composites</topic><topic>Scanning electron microscopy</topic><topic>Sorption</topic><topic>Sorption cycling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kurko, Sandra</creatorcontrib><creatorcontrib>Aurora, Annalisa</creatorcontrib><creatorcontrib>Gattia, Daniele Mirabile</creatorcontrib><creatorcontrib>Contini, Vittoria</creatorcontrib><creatorcontrib>Montone, Amelia</creatorcontrib><creatorcontrib>Rašković-Lovre, Željka</creatorcontrib><creatorcontrib>Novaković, Jasmina Grbović</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>International journal of hydrogen energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kurko, Sandra</au><au>Aurora, Annalisa</au><au>Gattia, Daniele Mirabile</au><au>Contini, Vittoria</au><au>Montone, Amelia</au><au>Rašković-Lovre, Željka</au><au>Novaković, Jasmina Grbović</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen sorption properties of MgH2/NaBH4 composites</atitle><jtitle>International journal of hydrogen energy</jtitle><date>2013-09-10</date><risdate>2013</risdate><volume>38</volume><issue>27</issue><spage>12140</spage><epage>12145</epage><pages>12140-12145</pages><issn>0360-3199</issn><eissn>1879-3487</eissn><coden>IJHEDX</coden><abstract>The hydrogen sorption properties of magnesium hydride–sodium borohydride composites prepared by means of high-energy ball milling under Ar atmosphere were investigated. Mutual influence of milling time and the content of NaBH4 were studied. Microstructural and morphological analyses were carried out using X-ray Diffraction (XRD), laser scattering measurements and Scanning Electron Microscopy (SEM), while kinetic analysis and cycling were performed in a Sievert's volumetric apparatus. It has been shown that low content of NaBH4 and short milling time are beneficial for hydrogen sorption kinetics.
•Ball milling with NaBH4 significantly improves MgH2 hydrogen sorption kinetics.•Composite has very good hydrogen cycling properties.•Concentration of catalyst and milling time are important for kinetics improvement.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ijhydene.2013.04.075</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0360-3199 |
| ispartof | International journal of hydrogen energy, 2013-09, Vol.38 (27), p.12140-12145 |
| issn | 0360-3199 1879-3487 |
| language | eng |
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| source | ScienceDirect Journals |
| subjects | Alternative fuels. Production and utilization Applied sciences Ball milling Diffraction Energy Exact sciences and technology Fuels Hydrogen Hydrogen storage Hydrogen-based energy Kinetics Lasers Magnesium MgH2/NaBH4 composites Scanning electron microscopy Sorption Sorption cycling |
| title | Hydrogen sorption properties of MgH2/NaBH4 composites |
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