Preparation and characterization of nanoporous carbon-supported platinum as anode electrocatalyst for direct borohydride fuel cell

• Published in: International journal of hydrogen energy 2014-04, Vol.39 (12), p.6729-6736
• Main Authors: Liu, Jing, Wang, Hao, Wu, Chun, Zhao, Qinglan, Wang, Xianyou, Yi, Lanhua
• Format: Article
• Language: English
• Subjects: Alternative fuels. Production and utilization; Anodes; Applied sciences; Borohydrides; Carbon; Catalysts; Electrocatalysts; Energy; Exact sciences and technology; Fuel cells; Fuels; Hydrogen; Nanostructure; Platinum
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2014.01.200

The nanoporous carbon (NPC) is synthesized by carbonization of metal-organic framework-5 (MOF-5, [Zn sub(4)O(bdc) sub(3)], bdc = 1,4-benzenedicarboxylate) with furfuryl alcohol (FA) as carbon source and used as the carrier of the anode catalyst for the direct borohydride-hydrogen peroxide fuel cell (DBHFC). Then the NPC-supported Pt anode catalyst (Pt/NPC) is firstly prepared by a modified NaBH sub(4) reduction method. The obtained Pt/NPC catalyst is characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive spectrometry (EDS), cyclic voltammetry, chronopotentiometry, chronoamperometry and fuel cell test. The results show that the Pt/NPC is made up of the spherical Pt nanoparticles which disperse uniformly on the surface of the NPC with average size 2.38 nm, and exhibits 36.38% higher current density for directly borohydride oxidation than the Vulcan XC-72 carbon supported Pt (Pt/XC-72). Besides, the DBHFC using the Pt/NPC as anode electrocatalyst shows the maximum power density as high as 54.34 mW cm super(-2) at 25 degree C.