Extraction Joined with Adsorption and Catalytic Oxidation of Dibenzothiophene with Commercially Available Tungsten Carbide

Extraction with ionic liquids joined with adsorption and catalytic oxidation composed with commercially available tungsten carbide, 30% H2O2 and 1-n-octyl-3-methylimidazolium hexafluorophosphate ([omim]PF6) could achieve the ultra-deep removal of dibenzothiophene (DBT) in model oil. In the case of t...

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Published in:Key engineering materials 2014-01, Vol.575-576, p.539-542
Main Authors: Xu, Ye Hai, Zhou, Jian Jun, Chao, Yan Hong, Li, Hua Ming, Jiang, Xin Chun, Yan, Shan, Chen, Xiao Jun, Zhu, Wen Shuai, Zhou, Ting
Format: Article
Language:English
Subjects:
Adsorption
Catalysis
Catalysts
Dibenzothiophene
Oxidation
Recycled
Solvent extraction
Tungsten carbide
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cited_by cdi_FETCH-LOGICAL-c414t-f5375a1029541d299c6204c2351beede0a81f52a638371ebd25094f15bbc50d43
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creator Xu, Ye Hai
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description Extraction with ionic liquids joined with adsorption and catalytic oxidation composed with commercially available tungsten carbide, 30% H2O2 and 1-n-octyl-3-methylimidazolium hexafluorophosphate ([omim]PF6) could achieve the ultra-deep removal of dibenzothiophene (DBT) in model oil. In the case of the system increased the sulfur removal to 100% for 1h, which was remarkably superior to mere solvent extraction with IL (29.4%) or adsorption and catalytic oxidation without IL (2.0%). Especially, we found that the removal of 4,6-DMDBT could be up to 100%. The system could be recycled at least 12 times and the deep removal of DBT still could be achieved.
doi_str_mv 10.4028/www.scientific.net/KEM.575-576.539
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subjects Adsorption
Catalysis
Catalysts
Dibenzothiophene
Oxidation
Recycled
Solvent extraction
Tungsten carbide
title Extraction Joined with Adsorption and Catalytic Oxidation of Dibenzothiophene with Commercially Available Tungsten Carbide
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