The effect of pre-strain on hydrogen embrittlement in 310S stainless steel

• Published in: Journal of alloys and compounds 2014-06, Vol.598, p.205-212
• Main Authors: Ji, Hyunju, Park, Il-Jeong, Lee, Sang-Min, Lee, Young-Kook
• Format: Article
• Language: English
• Subjects: Applied sciences; Austenitic stainless steel; Austenitic stainless steels; Elongation; Exact sciences and technology; Fracture mechanics; Fractures; Hydrogen charging; Hydrogen embrittlement; Hydrogen storage; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Mechanical twin; Metals. Metallurgy; Pre-strain; Strain hardening; Tensile deformation; Twin boundaries
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2014.02.038

•Pre-straining increased the resistance to hydrogen embrittlement (HE) in STS 310S.•The improved HE was due to the suppression of a ductile to brittle fracture transition.•Ductility was kept due to suppressed twinning and hydrogen delivery by pre-strain. The effect of pre-strain on hydrogen embrittlement (HE) was investigated using STS 310S, considering its application to a ferrous cylinder liner for hydrogen storage. Whereas tensile strength was insignificantly influenced by hydrogen charging, elongation was decreased due to a ductile to brittle fracture transition. However, the degree of the reduction in elongation by hydrogen charging was decreased with increasing pre-strain, indicating that pre-straining improved the resistance to HE by suppressing the fracture transition. The cause for suppression of the fracture transition by pre-strain was investigated through the analyses of strain hardening behavior and thermal desorption of hydrogen. The strain hardening rate curves of annealed and pre-strained specimens was divided into several stages, which were greatly affected by primary and secondary twinning, regardless of hydrogen charging. This strain hardening analysis showed that pre-straining suppressed mechanical twinning during tensile deformation. The thermal desorption analysis revealed that the migration of diffusible hydrogen atoms to twin boundaries was hindered by pre-strain. Therefore, the reason why pre-strain suppressed the fracture transition to improve the resistance to HE was because pre-strain hindered both mechanical twinning during tensile deformation and hydrogen delivery to twin boundaries not to form highly hydrogen-concentrated twin boundaries.