What Currently Limits Charge Carrier Mobility in Crystals of Molecular Semiconductors?

Charge carrier mobility is a central property that characterizes the performances of organic semiconductors and is mostly measured in field‐effect transistors. High mobility values are sought by many research teams. This article, that provides an overview of best performing molecular semiconductors...

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Published in:Israel journal of chemistry 2014-06, Vol.54 (5-6), p.595-620
Main Authors: Schweicher, Guillaume, Olivier, Yoann, Lemaur, Vincent, Geerts, Yves Henri
Format: Article
Language:English
Subjects:
charge carrier mobility
Charge carriers
charge transfer
Construction
Crystals
electrochemistry
Field effect transistors
Organic semiconductors
Semiconductor devices
Semiconductors
structureactivity relationships
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description Charge carrier mobility is a central property that characterizes the performances of organic semiconductors and is mostly measured in field‐effect transistors. High mobility values are sought by many research teams. This article, that provides an overview of best performing molecular semiconductors is constructed on the question: What currently limits charge carrier mobility in crystals of molecular semiconductors? With this in mind, we confront, in a critical way, the current theoretical understanding to the most salient experimental results with the hope to reach a deeper understanding based on first principles and order of magnitudes of the main physical parameters.
doi_str_mv 10.1002/ijch.201400047
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source Wiley-Blackwell Read & Publish Collection
subjects charge carrier mobility
Charge carriers
charge transfer
Construction
Crystals
electrochemistry
Field effect transistors
Organic semiconductors
Semiconductor devices
Semiconductors
structureactivity relationships
title What Currently Limits Charge Carrier Mobility in Crystals of Molecular Semiconductors?
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