Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s

A new method of the synthesis of oligo(tetramethylene succinate-co-carbonate) diols using dimethyl succinate, 1,4-butanediol and tetramethylene bis(methyl carbonate) was elaborated. The resultant oligomerols (Mn = 2600- 3700) were characterized by FTIR, H NMR, GPC and DSC analysis. Depending on the...

Full description

Saved in:
Bibliographic Details
Published in:Polish journal of chemical technology 2013-01, Vol.15 (4), p.80-88
Main Authors: Mazurek, Magdalena M., Rokicki, Gabriel
Format: Article
Language:English
Subjects:
Biodegradability
biodegradation
Carbonates
Crystal structure
Dimethyl
oligo(ester-carbonate) diol
Phase (cyclic)
polyurethane
Polyurethane resins
Resultants
Synthesis
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c462t-a1f0ed38474d0eca2660bf3612076df12990c3666a1976537bd82ea2b18632a3
cites
container_end_page 88
container_issue 4
container_start_page 80
container_title Polish journal of chemical technology
container_volume 15
creator Mazurek, Magdalena M.
Rokicki, Gabriel
description A new method of the synthesis of oligo(tetramethylene succinate-co-carbonate) diols using dimethyl succinate, 1,4-butanediol and tetramethylene bis(methyl carbonate) was elaborated. The resultant oligomerols (Mn = 2600- 3700) were characterized by FTIR, H NMR, GPC and DSC analysis. Depending on the content of carbonate units in the polymer molecules, the melting point of the crystalline phase changes significantly. The synthesis of poly(ester-carbonate-urea-urethane)s was carried out with two aliphatic diisocyanates - cyclic IPDI or linear HDI. The resultant products exhibited very good mechanical properties - tensile strength up to 60 MPa and elongation at break about 500%. Preliminary studies confirmed that the presence of ester units in the soft segments as well as lack of crystalline phase significantly enhances the biodegradability of the PUR in comparison to that of polyurethanes based on carbonate oligomers.
doi_str_mv 10.2478/pjct-2013-0073
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1671611849</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1620036073</sourcerecordid><originalsourceid>FETCH-LOGICAL-c462t-a1f0ed38474d0eca2660bf3612076df12990c3666a1976537bd82ea2b18632a3</originalsourceid><addsrcrecordid>eNqNUU1LxTAQDKLg8-PqueBFD9HdJE1SPIn4BYIX7yFtU-2jr6lJq7x_b0o9iHjwsruws8PsDCEnCBdMKH05rKuRMkBOARTfISvURUGFErib5hwKqhHVPjmIcQ2QKy3EitSP_YeLY_tqx9b3MfN9Nr65LG771GIbM9vX2RD84MLYurRvsrL1tXsNtrZl57LBd9uzxOACrWwofW9HR6fg7FzGN9u783hE9hrbRXf83Q_Jy93ty80DfXq-f7y5fqKVkGykFhtwNddJcg2uskxKKBsukYGSdYOsKKDiUkqLhZI5V2WtmbOsRC05s_yQnC20Se_7lDSZTRsr13VJhJ-iQalQImpR_APKALhMPibo6S_o2k-hT38YFFoVGgXLE-piQVXBxxhcY4bQbmzYGgQzx2PmeMwcj4GF9mo5-LRdMm92dNqm4Qf7n4eYCw38C_1Alxw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1487981425</pqid></control><display><type>article</type><title>Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s</title><source>Publicly Available Content Database</source><creator>Mazurek, Magdalena M. ; Rokicki, Gabriel</creator><creatorcontrib>Mazurek, Magdalena M. ; Rokicki, Gabriel</creatorcontrib><description>A new method of the synthesis of oligo(tetramethylene succinate-co-carbonate) diols using dimethyl succinate, 1,4-butanediol and tetramethylene bis(methyl carbonate) was elaborated. The resultant oligomerols (Mn = 2600- 3700) were characterized by FTIR, H NMR, GPC and DSC analysis. Depending on the content of carbonate units in the polymer molecules, the melting point of the crystalline phase changes significantly. The synthesis of poly(ester-carbonate-urea-urethane)s was carried out with two aliphatic diisocyanates - cyclic IPDI or linear HDI. The resultant products exhibited very good mechanical properties - tensile strength up to 60 MPa and elongation at break about 500%. Preliminary studies confirmed that the presence of ester units in the soft segments as well as lack of crystalline phase significantly enhances the biodegradability of the PUR in comparison to that of polyurethanes based on carbonate oligomers.</description><identifier>ISSN: 1509-8117</identifier><identifier>EISSN: 1899-4741</identifier><identifier>DOI: 10.2478/pjct-2013-0073</identifier><language>eng</language><publisher>Szczecin: Versita</publisher><subject>Biodegradability ; biodegradation ; Carbonates ; Crystal structure ; Dimethyl ; oligo(ester-carbonate) diol ; Phase (cyclic) ; polyurethane ; Polyurethane resins ; Resultants ; Synthesis</subject><ispartof>Polish journal of chemical technology, 2013-01, Vol.15 (4), p.80-88</ispartof><rights>Copyright Versita 2013</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c462t-a1f0ed38474d0eca2660bf3612076df12990c3666a1976537bd82ea2b18632a3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.proquest.com/docview/1487981425?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,25731,27901,27902,36989,36990,44566</link.rule.ids></links><search><creatorcontrib>Mazurek, Magdalena M.</creatorcontrib><creatorcontrib>Rokicki, Gabriel</creatorcontrib><title>Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s</title><title>Polish journal of chemical technology</title><description>A new method of the synthesis of oligo(tetramethylene succinate-co-carbonate) diols using dimethyl succinate, 1,4-butanediol and tetramethylene bis(methyl carbonate) was elaborated. The resultant oligomerols (Mn = 2600- 3700) were characterized by FTIR, H NMR, GPC and DSC analysis. Depending on the content of carbonate units in the polymer molecules, the melting point of the crystalline phase changes significantly. The synthesis of poly(ester-carbonate-urea-urethane)s was carried out with two aliphatic diisocyanates - cyclic IPDI or linear HDI. The resultant products exhibited very good mechanical properties - tensile strength up to 60 MPa and elongation at break about 500%. Preliminary studies confirmed that the presence of ester units in the soft segments as well as lack of crystalline phase significantly enhances the biodegradability of the PUR in comparison to that of polyurethanes based on carbonate oligomers.</description><subject>Biodegradability</subject><subject>biodegradation</subject><subject>Carbonates</subject><subject>Crystal structure</subject><subject>Dimethyl</subject><subject>oligo(ester-carbonate) diol</subject><subject>Phase (cyclic)</subject><subject>polyurethane</subject><subject>Polyurethane resins</subject><subject>Resultants</subject><subject>Synthesis</subject><issn>1509-8117</issn><issn>1899-4741</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNqNUU1LxTAQDKLg8-PqueBFD9HdJE1SPIn4BYIX7yFtU-2jr6lJq7x_b0o9iHjwsruws8PsDCEnCBdMKH05rKuRMkBOARTfISvURUGFErib5hwKqhHVPjmIcQ2QKy3EitSP_YeLY_tqx9b3MfN9Nr65LG771GIbM9vX2RD84MLYurRvsrL1tXsNtrZl57LBd9uzxOACrWwofW9HR6fg7FzGN9u783hE9hrbRXf83Q_Jy93ty80DfXq-f7y5fqKVkGykFhtwNddJcg2uskxKKBsukYGSdYOsKKDiUkqLhZI5V2WtmbOsRC05s_yQnC20Se_7lDSZTRsr13VJhJ-iQalQImpR_APKALhMPibo6S_o2k-hT38YFFoVGgXLE-piQVXBxxhcY4bQbmzYGgQzx2PmeMwcj4GF9mo5-LRdMm92dNqm4Qf7n4eYCw38C_1Alxw</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Mazurek, Magdalena M.</creator><creator>Rokicki, Gabriel</creator><general>Versita</general><general>De Gruyter Poland</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BYOGL</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>L7M</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PIMPY</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7T7</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>KR7</scope></search><sort><creationdate>20130101</creationdate><title>Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s</title><author>Mazurek, Magdalena M. ; Rokicki, Gabriel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c462t-a1f0ed38474d0eca2660bf3612076df12990c3666a1976537bd82ea2b18632a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Biodegradability</topic><topic>biodegradation</topic><topic>Carbonates</topic><topic>Crystal structure</topic><topic>Dimethyl</topic><topic>oligo(ester-carbonate) diol</topic><topic>Phase (cyclic)</topic><topic>polyurethane</topic><topic>Polyurethane resins</topic><topic>Resultants</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mazurek, Magdalena M.</creatorcontrib><creatorcontrib>Rokicki, Gabriel</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>ProQuest Pharma Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>East Europe, Central Europe Database</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest Central (New)</collection><collection>ProQuest One Academic (New)</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Middle East (New)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Applied &amp; Life Sciences</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Civil Engineering Abstracts</collection><jtitle>Polish journal of chemical technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mazurek, Magdalena M.</au><au>Rokicki, Gabriel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s</atitle><jtitle>Polish journal of chemical technology</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>15</volume><issue>4</issue><spage>80</spage><epage>88</epage><pages>80-88</pages><issn>1509-8117</issn><eissn>1899-4741</eissn><abstract>A new method of the synthesis of oligo(tetramethylene succinate-co-carbonate) diols using dimethyl succinate, 1,4-butanediol and tetramethylene bis(methyl carbonate) was elaborated. The resultant oligomerols (Mn = 2600- 3700) were characterized by FTIR, H NMR, GPC and DSC analysis. Depending on the content of carbonate units in the polymer molecules, the melting point of the crystalline phase changes significantly. The synthesis of poly(ester-carbonate-urea-urethane)s was carried out with two aliphatic diisocyanates - cyclic IPDI or linear HDI. The resultant products exhibited very good mechanical properties - tensile strength up to 60 MPa and elongation at break about 500%. Preliminary studies confirmed that the presence of ester units in the soft segments as well as lack of crystalline phase significantly enhances the biodegradability of the PUR in comparison to that of polyurethanes based on carbonate oligomers.</abstract><cop>Szczecin</cop><pub>Versita</pub><doi>10.2478/pjct-2013-0073</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1509-8117
ispartof Polish journal of chemical technology, 2013-01, Vol.15 (4), p.80-88
issn 1509-8117
1899-4741
language eng
recordid cdi_proquest_miscellaneous_1671611849
source Publicly Available Content Database
subjects Biodegradability
biodegradation
Carbonates
Crystal structure
Dimethyl
oligo(ester-carbonate) diol
Phase (cyclic)
polyurethane
Polyurethane resins
Resultants
Synthesis
title Investigations on the synthesis and properties of biodegradable poly(ester-carbonate-urea-urethane)s
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-23T13%3A24%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigations%20on%20the%20synthesis%20and%20properties%20of%20biodegradable%20poly(ester-carbonate-urea-urethane)s&rft.jtitle=Polish%20journal%20of%20chemical%20technology&rft.au=Mazurek,%20Magdalena%20M.&rft.date=2013-01-01&rft.volume=15&rft.issue=4&rft.spage=80&rft.epage=88&rft.pages=80-88&rft.issn=1509-8117&rft.eissn=1899-4741&rft_id=info:doi/10.2478/pjct-2013-0073&rft_dat=%3Cproquest_cross%3E1620036073%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c462t-a1f0ed38474d0eca2660bf3612076df12990c3666a1976537bd82ea2b18632a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1487981425&rft_id=info:pmid/&rfr_iscdi=true