Reversible thermochromic switching of fluorescent poly(vinylidene fluoride) composite containing bis(benzoxazolyl)stilbene dye

• Published in: Dyes and pigments 2013-10, Vol.99 (1), p.99-104
• Main Authors: Bao, Suping, Fei, Bin, Li, Jianhua, Yao, Xing, Lu, Xinkun, Xin, John H.
• Format: Article
• Language: English
• Subjects: Bis(benzoxazolyl)stilbene; Composite; Conversion; Cooling; Dispersions; Dyes; Emission; Fluorescence; Fluorides; Melts; Poly(vinylidene fluoride); Reversible; Switching; Thermochromism
• ISSN: 0143-7208; 1873-3743
• DOI: 10.1016/j.dyepig.2013.04.005

A series of fluorescent composites was prepared via melt compounding poly(vinylidene fluoride) with 4,4′-bis(2-benzoxazolyl)stilbene. The composite containing moderate amount of the stilbene (e.g. 0.5 wt%) exhibited a reversible thermochromic transition between blue and green fluorescence. The composite emitted green light upon UV excitation at room temperature, while it changed to blue at the temperature above the melting point of the poly(vinylidene fluoride). Upon cooling to room temperature, an intense green emission was regenerated. Such a conversion between green and blue shades was reproducible via repeated heating and cooling cycles. This thermochromic switching was found to originate from the dispersion of dye molecules in the composite. Reversible fluorescence switching between green and blue colors of the fabricated composite is reproducible over repeated heating and cooling cycles. [Display omitted] •Fluorescent composites were prepared via a facile blending approach.•A reversible thermally-induced fluorescent conversion was reported.•Blue-green fluorescence switching was reproducible over repeated thermal cycles.•The fluorescent switching was highly related to dye dispersion in polymer matrix.