Assessment of role of morphology in gas permselectivity of membranes based on polypropylene/ethylene vinyl acetate/clay nanocomposite

• Published in: Journal of membrane science 2013-10, Vol.445, p.76-87
• Main Authors: Goodarzi, Vahabodin, Hassan Jafari, Seyed, Ali Khonakdar, Hossein, Ghalei, Behnam, Mortazavi, Mehdi
• Format: Article
• Language: English
• Subjects: acetates; annealing; Applied sciences; artificial membranes; Carbon dioxide; Chemistry; clay; Colloidal state and disperse state; Composites; crystal structure; droplet size; Droplets; Ethylene vinyl acetates; ethylene-vinyl acetate; Exact sciences and technology; Forms of application and semi-finished materials; Gas permeability; Gas separation; gases; General and physical chemistry; Membrane; Membranes; Morphology; Nanocomposites; Nanostructure; nitrogen; oxygen; Permeability; Polymer industry, paints, wood; Polypropylenes; scanning electron microscopy; solubility; Technology of polymers; transmission electron microscopy; X-ray diffraction
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2013.04.073

This paper reports on the influence of morphology on gas permeability and selectivity of membranes made from polypropylene (PP)/ethylene vinyl acetate copolymer (EVA)/clay (OMMT) nanocomposites. The morphology was adjusted by variation in the EVA (25, 50wt%), OMMT (0 and 5wt%) and compatibilizer (PP-g-MAH) (0 and 5wt%) contents. Gas permeation properties of membranes with different morphologies, were studied for pure CO2, O2 and N2 gases. X-ray diffraction (XRD) patterns showed no changes in crystalline structure of samples. TEM analysis confirmed high tendency of OMMT flacks for locating in the EVA phase. SEM results revealed that an increase in OMMT loading decreases the EVA droplet size (Dn) in samples with droplet type morphology and increases continuity index of EVA (CCI) in the samples with co-continuous morphology. Changes in compatibilizer/OMMT ratio imposed a dual effect on the morphology of the system with respect to Dn and CCI. A good correlation could be established between these morphological parameters with gas solubility parameters, gas permeability and CO2/N2 as well as CO2/O2 gas selectivity. Annealing was shown to change the morphology which in turn had a very strong influence on the membranes gas permeability behavior. [Display omitted] •Role of morphology in performance of nanostructured PP/EVA membranes was explored.•Annealing was highly influential on permeability properties by changing morphology.•Increase in dispersed phase size increased gas permeability and selectivity.•Increase in co-continuity index reduced gas permeability, while raised selectivity.•Proposed a schematic model for describing gas permeability and selectivity.