A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [V(V)(μ₃-O)₄V(IV)₄O₅(SO₄)₄(en)]⁵⁻ anions

A new vanadium sulfate, [H2N(CH3)2](19/3)(en)[V5O5(μ3-O)4(SO4)4](SO4)(2/3)[HN(CH3)2](2/3) 1, constructed from novel umbrella-like [V(V)(μ3-O)4V(IV)4O5(SO4)4(en)](5-) anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indic...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2015-05, Vol.44 (18), p.8605-8608
Main Authors: Zhou, Shuai, Wan, Hongxiang, Hu, Gonghao, Zhang, Yu, Liu, Ying, Miao, Hao, Zhu, Dunru, Xu, Yan
Format: Article
Language:English
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Summary:A new vanadium sulfate, [H2N(CH3)2](19/3)(en)[V5O5(μ3-O)4(SO4)4](SO4)(2/3)[HN(CH3)2](2/3) 1, constructed from novel umbrella-like [V(V)(μ3-O)4V(IV)4O5(SO4)4(en)](5-) anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.
ISSN:1477-9226
1477-9234
DOI:10.1039/c5dt01026h