Electrochemically Informed Synthesis: Oxidation versus Coordination of 5,6-Bis(phenylchalcogeno)acenaphthenes

Chalcogen dications: Facile synthesis of EE bonded dications can be readily achieved. Radical cations are identified as the intermediates.

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Bibliographic Details
Published in:Chemphyschem 2013-10, Vol.14 (14), p.3199-3203
Main Authors: Knight, Fergus R., Randall, Rebecca A. M., Roemmele, Tracey L., Boeré, René T., Bode, Bela E., Crawford, Luke, Bühl, Michael, Slawin, Alexandra M. Z., Woollins, J. Derek
Format: Article
Language:English
Subjects:
1,2‐dications
2-dications
chalcogens
Chemistry
density functional calculations
Electrochemistry
electron paramagnetic resonance spectroscopy
Exact sciences and technology
General and physical chemistry
Oxidation
radicals
Synthesis
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Description
Summary:Chalcogen dications: Facile synthesis of EE bonded dications can be readily achieved. Radical cations are identified as the intermediates.
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.201300678