Microporous polymer network films covalently bound to gold electrodes

Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the fi...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (20), p.4283-4286
Main Authors: Becker, Daniel, Heidary, Nina, Horch, Marius, Gernert, Ulrich, Zebger, Ingo, Schmidt, Johannes, Fischer, Anna, Thomas, Arne
Format: Article
Language:English
Subjects:
Attachment
Binding
Coatings
Covalence
Electrodes
Gold
Networks
Polymeric films
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Summary:Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc09637a