Microwave Assisted Synthesis, and Structure of a Co-Crystal Nickel Complex with 2-ethoxy-6-methyliminomethyl-phenol

A new co-crystal complex [Ni 7 (emmp) 6 (OH) 6 ][Ni(emmp) 2 ]·(CH 3 CN) 2 ·(ClO 4 ) 2 (1, Hemmp is 2-ethoxy-6-methyliminom-ethyl-phenol) has been synthesized by microwave-assist solvothermal method. Complex 1 was characterized by IR spectroscopy, elemental analysis, and X-ray single-crystal diffract...

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Bibliographic Details
Published in:Molecular Crystals and Liquid Crystals 2015-01, Vol.607 (1), p.242-249
Main Authors: Yu, Xiao, Pu, Huang, Qing, Liu Yi
Format: Article
Language:English
Subjects:
Acetonitrile
Clusters
Co-crystal complex
Crystals
Diffraction
Hydrogen bonds
hydrogen bonds, microwave chemistry
Infrared radiation
Liquid crystals
Microwaves
Molecules
N,O ligands
Spectrum analysis
X-rays
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Summary:A new co-crystal complex [Ni 7 (emmp) 6 (OH) 6 ][Ni(emmp) 2 ]·(CH 3 CN) 2 ·(ClO 4 ) 2 (1, Hemmp is 2-ethoxy-6-methyliminom-ethyl-phenol) has been synthesized by microwave-assist solvothermal method. Complex 1 was characterized by IR spectroscopy, elemental analysis, and X-ray single-crystal diffraction. The 1 was consist of a nano-bowl-like heptanuclear cation cluster [Ni 7 (emmp) 6 (OH) 6 ] 2+ , two counterion ClO 4 − , one neutral mononuclear complex [Ni(emmp) 2 ] and two acetonitrile molecules. The five part of 1 constructed a whole through M···H interaction, O-H···N hydrogen bonds and C-H···O hydrogen bonds.
ISSN:1542-1406
1563-5287
1527-1943
DOI:10.1080/15421406.2014.930223