Recycling Tires? Reversible Crosslinking of Poly(butadiene)

Furan‐modified poly(butadiene) prepared by the thiol‐ene click reaction is crosslinked with bismaleimides through the Diels–Alder reaction, giving rise to a novel recyclable elastomer. This is possible because of the thermal reversibility of the adducts responsible for the formation of the network....

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2015-04, Vol.27 (13), p.2242-2245
Main Authors: Trovatti, Eliane, Lacerda, Talita M., Carvalho, Antonio J. F., Gandini, Alessandro
Format: Article
Language:English
Subjects:
Bismaleimides
Crosslinking
Diels-Alder reactions
Formations
furan/maleimide
Networks
poly(butadiene)
recyclable elastomers
Recycling
reversible crosslinking
Strategy
Tires
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Summary:Furan‐modified poly(butadiene) prepared by the thiol‐ene click reaction is crosslinked with bismaleimides through the Diels–Alder reaction, giving rise to a novel recyclable elastomer. This is possible because of the thermal reversibility of the adducts responsible for the formation of the network. The use of this strategy provides the possibility to produce recyclable tires.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201405801