High-resolution slice selection NMR for the measurement of CO sub(2) diffusion under non-equilibrium conditions

We present a simple and an efficient approach using spatially selective NMR to investigate solvation and diffusion of CO sub(2) in ionic liquids. The techniques demonstrated here are shown as novel and effective means of studying solvated gas dynamics under non-equilibrium conditions without the nee...

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Bibliographic Details
Published in:Magnetic resonance in chemistry 2015-03, Vol.53 (3), p.200-202
Main Authors: Allen, Jesse, Damodaran, Krishnan
Format: Article
Language:English
Subjects:
Carbon dioxide
Diffusion
Gas dynamics
Ionic liquids
Magnetic resonance
Nuclear magnetic resonance
Solvation
Online Access:Get full text
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Summary:We present a simple and an efficient approach using spatially selective NMR to investigate solvation and diffusion of CO sub(2) in ionic liquids. The techniques demonstrated here are shown as novel and effective means of studying solvated gas dynamics under non-equilibrium conditions without the need for conventional high power gradients. Copyright copyright 2014 John Wiley & Sons, Ltd. We present a simple and an efficient approach using spatially selective NMR to investigate solvation and diffusion of CO sub(2) in ionic liquids. The techniques demonstrated here are shown as novel and effective means of studying solvated gas dynamics under non-equilibrium conditions without the need for conventional high power gradients.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.4176