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Effectiveness of catechin and poly(ethylene glycol) at inhibiting the spontaneous combustion of coal
The effects of various combinations of catechin and poly(ethylene glycol) (PEG) concentrations on the inhibition of coal oxidation were studied. The oxidation behaviors of coal samples both with and without the additives were examined, based on measurements of cross point temperature, oxygen consump...
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Published in: | Fuel processing technology 2014-04, Vol.120, p.123-127 |
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container_title | Fuel processing technology |
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creator | Dou, Guolan Wang, Deming Zhong, Xiaoxing Qin, Botao |
description | The effects of various combinations of catechin and poly(ethylene glycol) (PEG) concentrations on the inhibition of coal oxidation were studied. The oxidation behaviors of coal samples both with and without the additives were examined, based on measurements of cross point temperature, oxygen consumption during low temperature oxidation and carbon monoxide emission rates. The results demonstrate that an additive consisting of a combination of both catechin and PEG 200 is capable of inhibiting the oxidation process. In situ monitoring of the surfaces of coal samples during oxidation also indicated that these additives suppress coal oxidation by accelerating the formation of ether bonds. Accordingly, a suppression mechanism is proposed. |
doi_str_mv | 10.1016/j.fuproc.2013.12.016 |
format | article |
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The oxidation behaviors of coal samples both with and without the additives were examined, based on measurements of cross point temperature, oxygen consumption during low temperature oxidation and carbon monoxide emission rates. The results demonstrate that an additive consisting of a combination of both catechin and PEG 200 is capable of inhibiting the oxidation process. In situ monitoring of the surfaces of coal samples during oxidation also indicated that these additives suppress coal oxidation by accelerating the formation of ether bonds. Accordingly, a suppression mechanism is proposed.</description><identifier>ISSN: 0378-3820</identifier><identifier>EISSN: 1873-7188</identifier><identifier>DOI: 10.1016/j.fuproc.2013.12.016</identifier><identifier>CODEN: FPTEDY</identifier><language>eng</language><publisher>Amsterdam: Elsevier</publisher><subject>Applied sciences ; Carbon monoxide ; Catechins ; Coal ; Combustion of solid fuels ; Combustion. Flame ; Emission ; Energy ; Energy. 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Thermal use of fuels</subject><subject>Ethers</subject><subject>Exact sciences and technology</subject><subject>Glycols</subject><subject>Monitoring</subject><subject>Oxidation</subject><subject>Theoretical studies. Data and constants. 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Flame</topic><topic>Emission</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Ethers</topic><topic>Exact sciences and technology</topic><topic>Glycols</topic><topic>Monitoring</topic><topic>Oxidation</topic><topic>Theoretical studies. Data and constants. 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subjects | Applied sciences Carbon monoxide Catechins Coal Combustion of solid fuels Combustion. Flame Emission Energy Energy. Thermal use of fuels Ethers Exact sciences and technology Glycols Monitoring Oxidation Theoretical studies. Data and constants. Metering |
title | Effectiveness of catechin and poly(ethylene glycol) at inhibiting the spontaneous combustion of coal |
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