The marriage of endo-cavity and exo-wall complexation provides a facile strategy for supramolecular polymerization

Butylated pillar[5]arene (1) and N,N'-bis(n-butyl)pyromellitic diimide (2) form a 2 : 1 sandwich-type complex external to the walls of the receptor ("exo-wall" complex). The marriage of exo-wall interactions and endo-cavity inclusion provides a new strategy for the construction of sup...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (16), p.3434-3437
Main Authors: Wang, Shilu, Wang, Yiliang, Chen, Zhenxia, Lin, Yuejian, Weng, Linhong, Han, Kang, Li, Jian, Jia, Xueshun, Li, Chunju
Format: Article
Language:English
Subjects:
Complexation
Construction
Diimide
Inclusions
Polymerization
Receptors
Strategy
Walls
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Summary:Butylated pillar[5]arene (1) and N,N'-bis(n-butyl)pyromellitic diimide (2) form a 2 : 1 sandwich-type complex external to the walls of the receptor ("exo-wall" complex). The marriage of exo-wall interactions and endo-cavity inclusion provides a new strategy for the construction of supramolecular polymers from unfunctionalized neutral receptors.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc08820d