Impedance analysis of porous carbon electrodes to predict rate capability of electric double-layer capacitors

• Published in: Journal of power sources 2014-12, Vol.267, p.411-420
• Main Authors: Yoo, Hyun Deog, Jang, Jong Hyun, Ryu, Ji Heon, Park, Yuwon, Oh, Seung M.
• Format: Article
• Language: English
• Subjects: Accessibility; Activated carbon; Applied sciences; Capacitors; Capacitors. Resistors. Filters; Carbon; Direct energy conversion and energy accumulation; Electric double-layer capacitor (EDLC); Electric potential; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Electrochemical impedance spectroscopy (EIS); Electrodes; Exact sciences and technology; Impedance; Ohmic; Porosity; Porous electrode; Rate capability; Transmission-line model with pore size distribution (TLM-PSD); Various equipment and components
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2014.05.058

Electrochemical impedance analysis is performed to predict the rate capability of two commercial activated carbon electrodes (RP20 and MSP20) for electric double-layer capacitor. To this end, ac impedance data are fitted with an equivalent circuit that comprises ohmic resistance and impedance of intra-particle pores. To characterize the latter, ionic accessibility into intra-particle pores is profiled by using the fitted impedance parameters, and the profiles are transformed into utilizable capacitance plots as a function of charge–discharge rate. The rate capability that is predicted from the impedance analysis is well-matched with that observed from a charge–discharge rate test. It is found that rate capability is determined by ionic accessibility as well as ohmic voltage drop. A lower value in ionic accessibility for MSP20 is attributed to smaller pore diameter, longer length, and higher degree of complexity in pore structure. [Display omitted] •Rate capability of EDLC was quantitatively predicted by an impedance measurement.•Ohmic resistance and pores' ionic accessibility were factorized by EIS.•From the two factors, ohmic voltage drop and utilizable capacitance was derived.•A key formula was devised to correlate the ac with dc information of EDLC.•Thus predicted rate capabilities were verified by comparing with cell test results.