Effect of iron(III) nitrate concentration on tungsten chemical-mechanical-planarization performance

•We analyzed the W polishing mechanism on the Fe(NO3)3 concentration in H2O2 based acidic slurry.•The trend of the polishing rate was divided into two regions as a function of the Fe(NO3)3 concentration in H2O2 based slurry.•The trend of static etch rate is the opposite of that of the polishing rate...

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Bibliographic Details
Published in:Applied surface science 2013-10, Vol.282, p.512-517
Main Authors: Lim, Jae-Hyung, Park, Jin-Hyung, Park, Jea-Gun
Format: Article
Language:English
Subjects:
Catalyst
Chemical mechanical planarization
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Corrosion potential
Cross-disciplinary physics: materials science
rheology
Current density
Etching
Exact sciences and technology
Fe(NO3)3
Morphology
Oxidizer
Physics
Polishing
Slurries
Trends
Tungsten
Tungsten oxides
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Summary:•We analyzed the W polishing mechanism on the Fe(NO3)3 concentration in H2O2 based acidic slurry.•The trend of the polishing rate was divided into two regions as a function of the Fe(NO3)3 concentration in H2O2 based slurry.•The trend of static etch rate is the opposite of that of the polishing rate.•The trends of the W oxide layer content and corrosion current density were similar to the trend of polishing rate. Investigating the catalytic effect of Fe(NO3)3 on the performance of tungsten (W) chemical mechanical planarization in H2O2-based acidic slurries, we found that the trend of the polishing rate with increasing Fe(NO3)3 concentration was divided into two regions. The polishing rate in region I (0.10wt%), on the other hand, increased only slightly with increasing Fe(NO3)3 concentration. We suggest the excess ferric ions in the slurry were rapidly supplied to the W surface. Consequently, the addition of Fe(NO3)3 resulted in the rapid formation of the WO3 layer because of the decomposition of H2O2 into O2 by Fe3+ ion, and polishing rate increased with the Fe(NO3)3 concentration. This polishing trend was explained through the opposite trend of static etch rate, the confirmation of the surface morphology, the trend of the WO3 content on the W surface, and the trend of the corrosion potential and the corrosion current density.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2013.06.003