Preparation of titanium peroxide and its selective adsorption property on cationic dyes

• Published in: Applied surface science 2014-02, Vol.292, p.576-582
• Main Authors: Zhao, Xiao-guang, Huang, Ji-guo, Wang, Bo, Bi, Qiang, Dong, Li-li, Liu, Xing-juan
• Format: Article
• Language: English
• Subjects: Adsorption; Cationic dyes; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Kinetics; Peroxides; Physics; Reaction kinetics; Selective adsorption; Surface chemistry; Titanium; Titanium peroxide; X-ray photoelectron spectroscopy; X-rays
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2013.12.011

•Preparation and characterization of titanium peroxide powder.•Great selective adsorption property of titanium peroxide on cationic dyes.•The adsorption of methylene blue, malachite green, neutral red, methyl orange and phenol by titanium peroxide.•Adsorption equilibrium, kinetics and mechanism of titanium peroxide on methylene blue, malachite green and neutral red. Titanium peroxide powder was prepared with the reaction of titanium sulfate and H2O2 and showed good selective adsorption property on cationic dyes. The obtained material was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermogravimetric and differential scanning calorimetry (TG-DSC). The selective adsorption property was confirmed and evaluated by adsorption experiments of methyl orange (MO), phenol and three kinds of cationic dyes including methylene blue (MB), malachite green (MG) and neutral red (NR). The adsorption was very fast and adsorption equilibrium was reached in a very short time for all three cationic dyes. The adsorption kinetics of MB, MG and NR were studied then. It was found that the adsorption data fitted perfectly with the pseudo-second-order kinetics and the saturated adsorption capacities for MB, MG and NR were 224.37, 251.38 and 327.61mg/g at 25°C, respectively. The characterization and adsorption results indicated the controlling mechanism of adsorption processes could be electrostatic adsorption.