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Structural, Nonlinear Absorption, and Optical Limiting Properties of a New Organic Crystal 3-(3-fluorophenyl)-1-[4-(methylsulfanyl) phenyl] prop-2-en-1-one

This paper deals with the studies on synthesis, characterization, nonlinear absorption, and optical-limiting property of a new organic crystal 3-(3-fluorophenyl)-1-[ 4 -(methylsulfanyl) phenyl] prop-2-en-1-one (FMP). Primary characterization of FMP samples were performed using FTIR, UV-Visible, and...

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Bibliographic Details
Published in:Molecular Crystals and Liquid Crystals 2015-03, Vol.609 (1), p.192-204
Main Authors: Raghavendra, S., Dileep, C. S., Dharmaprakash, S. M.
Format: Article
Language:English
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Summary:This paper deals with the studies on synthesis, characterization, nonlinear absorption, and optical-limiting property of a new organic crystal 3-(3-fluorophenyl)-1-[ 4 -(methylsulfanyl) phenyl] prop-2-en-1-one (FMP). Primary characterization of FMP samples were performed using FTIR, UV-Visible, and NMR Spectroscopy techniques. FMP crystallizes in monoclinic system with centrosymmetric space group P2 1 /n. UV-Visible spectrum shows minimum absorption in the entire visible region. From the thermo gravimetric and differential scanning calorimetry, melting point of FMP was found to be 96°C and there was no phase transition below this temperature. Open aperture Z scan experiment of FMP showed a good nonlinear absorption and optical-limiting property.
ISSN:1542-1406
1563-5287
1527-1943
DOI:10.1080/15421406.2014.954323