Structural, Nonlinear Absorption, and Optical Limiting Properties of a New Organic Crystal 3-(3-fluorophenyl)-1-[4-(methylsulfanyl) phenyl] prop-2-en-1-one

This paper deals with the studies on synthesis, characterization, nonlinear absorption, and optical-limiting property of a new organic crystal 3-(3-fluorophenyl)-1-[ 4 -(methylsulfanyl) phenyl] prop-2-en-1-one (FMP). Primary characterization of FMP samples were performed using FTIR, UV-Visible, and...

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Published in:Molecular Crystals and Liquid Crystals 2015-03, Vol.609 (1), p.192-204
Main Authors: Raghavendra, S., Dileep, C. S., Dharmaprakash, S. M.
Format: Article
Language:English
Subjects:
chalcones
Characterization
Chemical synthesis
Constraining
crystal growth
Crystal structure
Crystallography
Differential scanning calorimetry
Fourier transforms
Infrared spectroscopy
NMR spectroscopy
nonlinear optical material
Nonlinearity
Optical properties
Organic crystals
Phenyls
Spectrum analysis
Temperature effects
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description This paper deals with the studies on synthesis, characterization, nonlinear absorption, and optical-limiting property of a new organic crystal 3-(3-fluorophenyl)-1-[ 4 -(methylsulfanyl) phenyl] prop-2-en-1-one (FMP). Primary characterization of FMP samples were performed using FTIR, UV-Visible, and NMR Spectroscopy techniques. FMP crystallizes in monoclinic system with centrosymmetric space group P2 1 /n. UV-Visible spectrum shows minimum absorption in the entire visible region. From the thermo gravimetric and differential scanning calorimetry, melting point of FMP was found to be 96°C and there was no phase transition below this temperature. Open aperture Z scan experiment of FMP showed a good nonlinear absorption and optical-limiting property.
doi_str_mv 10.1080/15421406.2014.954323
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1563-5287
1527-1943
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source EBSCOhost MLA International Bibliography With Full Text; Taylor and Francis Science and Technology Collection
subjects chalcones
Characterization
Chemical synthesis
Constraining
crystal growth
Crystal structure
Crystallography
Differential scanning calorimetry
Fourier transforms
Infrared spectroscopy
NMR spectroscopy
nonlinear optical material
Nonlinearity
Optical properties
Organic crystals
Phenyls
Spectrum analysis
Temperature effects
title Structural, Nonlinear Absorption, and Optical Limiting Properties of a New Organic Crystal 3-(3-fluorophenyl)-1-[4-(methylsulfanyl) phenyl] prop-2-en-1-one
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