A NbO-type metal-organic framework exhibiting high deliverable capacity for methane storage

A copper-based NbO-type metal-organic framework constructed from a tetracarboxylate incorporating phenylethyne as a spacer exhibited an exceptionally high methane working capacity of 184 cm(3) (STP) cm(-3) for methane storage. The value is among the highest reported for MOF materials.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-05, Vol.51 (40), p.8508-8511
Main Authors: Song, Chengling, Ling, Yajing, Feng, Yunlong, Zhou, Wei, Yildirim, Taner, He, Yabing
Format: Article
Language:English
Subjects:
Construction
Coordination Complexes - chemistry
Copper - chemistry
Metal-organic frameworks
Methane
Methane - chemistry
Niobium - chemistry
Spacers
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Description
Summary:A copper-based NbO-type metal-organic framework constructed from a tetracarboxylate incorporating phenylethyne as a spacer exhibited an exceptionally high methane working capacity of 184 cm(3) (STP) cm(-3) for methane storage. The value is among the highest reported for MOF materials.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01055a