meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone

Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels-Alder reaction. The basic optical properties of the pr...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2015-07, Vol.13 (25), p.6977-6983
Main Authors: Filatov, Mikhail A, Heinrich, Ernesta, Landfester, Katharina, Baluschev, Stanislav
Format: Article
Language:English
Subjects:
Anthraquinones - chemical synthesis
Anthraquinones - chemistry
Coordination Complexes - chemical synthesis
Coordination Complexes - chemistry
Cycloaddition Reaction
Isoindoles - chemistry
Palladium - chemistry
Porphyrins - chemical synthesis
Porphyrins - chemistry
Zinc - chemistry
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Summary:Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels-Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.
ISSN:1477-0520
1477-0539
DOI:10.1039/c5ob00884k