Very High Volume Fly Ash Cements. Early Age Hydration Study Using Na2SO4 as an Activator

The early age ambient temperature hydration of a hybrid cement formulation containing very high volumes of coal fly ash (~80% by dry mass) and activated by Na2SO4 is presented. The Na2SO4 salt acts as a safe and convenient in situ source of alkali to activate fly ash glassy phases without undesirabl...

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Bibliographic Details
Published in:Journal of the American Ceramic Society 2013-03, Vol.96 (3), p.900-906
Main Authors: Donatello, Shane, Fernández-Jimenez, Ana, Palomo, Angel
Format: Article
Language:English
Subjects:
Age
Cements
Compressive strength
Ettringite
Fly ash
Hydration
Pastes
Sand
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Summary:The early age ambient temperature hydration of a hybrid cement formulation containing very high volumes of coal fly ash (~80% by dry mass) and activated by Na2SO4 is presented. The Na2SO4 salt acts as a safe and convenient in situ source of alkali to activate fly ash glassy phases without undesirable effects on cement clinker hydration. Comparison to a reference paste with gypsum instead of sodium sulfate revealed that Na2SO4 reduced setting times, shortened the induction period, and increased early alite hydration and compressive strength development, but also restricted ettringite formation. When replacing the active fly ash component for milled sand of a similar particle size, the Na2SO4‐activated pastes set even quicker, no ettringite was observed, and early strengths were considerably reduced. Possible reaction mechanisms in the hybrid pastes are discussed.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.12178