Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids

The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinemen...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (60), p.11994-11996
Main Authors: McDonald, Kyle A, Feldblyum, Jeremy I, Koh, Kyoungmoo, Wong-Foy, Antek G, Matzger, Adam J
Format: Article
Language:English
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Summary:The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc03027g