Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids

The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinemen...

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Published in:Chemical communications (Cambridge, England) England), 2015-08, Vol.51 (60), p.11994-11996
Main Authors: McDonald, Kyle A, Feldblyum, Jeremy I, Koh, Kyoungmoo, Wong-Foy, Antek G, Matzger, Adam J
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Language:English
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cited_by cdi_FETCH-LOGICAL-c353t-5b01543f2b5b4ad7ebba877e98cb70efb2068ebee9ceb79c49d9e51a2c91d103
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container_end_page 11996
container_issue 60
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container_title Chemical communications (Cambridge, England)
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creator McDonald, Kyle A
Feldblyum, Jeremy I
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description The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.
doi_str_mv 10.1039/c5cc03027g
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title Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids
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