Bi-component CU sub(2)O-CuCl composites with tunable oxygen vacancies and enhanced photocatalytic properties

Bi-component Cu sub(2)O-CuCl composites with tunable oxygen vacancies contents have been successfully fabricated via the introduction of Cl source using a simple hydrothermal reduction method. The morphology, composition and structure of the prepared catalysts were characterized by FE-SEM, HR-TEM, E...

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Bibliographic Details
Published in:Applied catalysis. B, Environmental Environmental, 2015-07, Vol.170-171, p.225-232
Main Authors: Yang, Renchun, Lu, Xiaojia, Huang, Xiang, Chen, Zhiming, Zhang, Xu, Xu, Maodong, Song, Qingwu, Zhu, Lingting
Format: Article
Language:English
Subjects:
Catalysis
CATALYSTS
Charge carriers
COMPOSITES
COPPER OXIDE
CUPROUS OXIDE
Energy gaps (solid state)
Glucose
Iron
OXYGEN
Separation
VACANCIES
X RAY SPECTROSCOPY
X-ray photoelectron spectroscopy
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Summary:Bi-component Cu sub(2)O-CuCl composites with tunable oxygen vacancies contents have been successfully fabricated via the introduction of Cl source using a simple hydrothermal reduction method. The morphology, composition and structure of the prepared catalysts were characterized by FE-SEM, HR-TEM, EDS, XRD, XPS, EPR, UV-vis DRS and N sub(2) adsorption-desorption. The O/Cl ratios of the microcube Cu sub(2)O-CuCl composites can be easily tuned by the glucose amount. The results indicate that oxygen vacancies contents and E sub(g) values of the as-prepared samples are heavily dependent on the O/Cl ratios. Compared with the single component Cu sub(2)O sample, the Cu sub(2)O-CuCl composites show higher oxygen vacancies contents and narrower band gaps. These findings reveal that the introduction of Cl promotes the efficiencies of light harvest and charge carrier separation, ultimately enhancing the photodecoloration performance of MB.
ISSN:0926-3373
DOI:10.1016/j.apcatb.2015.01.046