Twin Polymerization at Spherical Hard Templates: An Approach to Size-Adjustable Carbon Hollow Spheres with Micro- or Mesoporous Shells

Kitset hollow spheres: The combination of twin polymerization with hard templates makes hollow carbon spheres (HCSs) with tailored properties easily accessible. The thickness and pore texture of the HCS shells and also the diameter of the spherical cavity can be varied. The application potential of...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-06, Vol.52 (23), p.6088-6091
Main Authors: Böttger-Hiller, Falko, Kempe, Patrick, Cox, Gerhard, Panchenko, Alexander, Janssen, Nicole, Petzold, Albrecht, Thurn-Albrecht, Thomas, Borchardt, Lars, Rose, Marcus, Kaskel, Stefan, Georgi, Colin, Lang, Heinrich, Spange, Stefan
Format: Article
Language:English
Subjects:
Accessibility
Carbon
Cycles
Holes
hollow carbon spheres
lithium-sulfur battery
Polymerization
Porosity
porous carbon
Surface layer
Texture
twin polymerization
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Summary:Kitset hollow spheres: The combination of twin polymerization with hard templates makes hollow carbon spheres (HCSs) with tailored properties easily accessible. The thickness and pore texture of the HCS shells and also the diameter of the spherical cavity can be varied. The application potential of synthesized HCS is substantiated by an excellent cycling stability of lithium–sulfur batteries.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201209849