Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

Baring all: The title reaction provides β‐naphthalenones bearing an all‐carbon quaternary center in good to excellent yields, as well as excellent chemo‐ and enantioselectivity (see scheme).

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-09, Vol.52 (38), p.10056-10059
Main Authors: Zhuo, Chun-Xiang, You, Shu-Li
Format: Article
Language:English
Subjects:
allylic dearomatization
arenes
asymmetric catalysis
Asymmetry
Bearing
Derivatives
Naphthol
palladium
synthetic methods
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Description
Summary:Baring all: The title reaction provides β‐naphthalenones bearing an all‐carbon quaternary center in good to excellent yields, as well as excellent chemo‐ and enantioselectivity (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201304591