Synthesis, Characterization, and Structures of a Persistent Aniline Radical Cation

Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6‐tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long CN bond beyond theoretical predi...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2012-11, Vol.51 (47), p.11878-11881
Main Authors: Chen, Xiaoyu, Wang, Xingyong, Sui, Yunxia, Li, Yizhi, Ma, Jing, Zuo, Jinglin, Wang, Xinping
Format: Article
Language:English
Subjects:
Aniline
anilines
Bonding
Cations
Crystal lattices
Isomers
radical ions
Radicals
Solid state
structure elucidation
Synthesis
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Summary:Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6‐tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long CN bond beyond theoretical prediction.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201205478