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Synthesis, Characterization, and Structures of a Persistent Aniline Radical Cation
Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6‐tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long CN bond beyond theoretical predi...
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Published in: | Angewandte Chemie International Edition 2012-11, Vol.51 (47), p.11878-11881 |
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container_title | Angewandte Chemie International Edition |
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creator | Chen, Xiaoyu Wang, Xingyong Sui, Yunxia Li, Yizhi Ma, Jing Zuo, Jinglin Wang, Xinping |
description | Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6‐tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long CN bond beyond theoretical prediction. |
doi_str_mv | 10.1002/anie.201205478 |
format | article |
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subjects | Aniline anilines Bonding Cations Crystal lattices Isomers radical ions Radicals Solid state structure elucidation Synthesis |
title | Synthesis, Characterization, and Structures of a Persistent Aniline Radical Cation |
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