Synthesis of meso-Substituted Tetrabenzotriazaporphyrins: Easy Access to Hybrid Macrocycles

Up to now, hybrid structures that lie between the ubiquitous phthalocyanine and porphyrin scaffolds have been extremely difficult to prepare. A straightforward, high‐yielding synthesis of meso‐derivatized tetrabenzotriazaporphyrins (see scheme) is described, thus unlocking access to this underdevelo...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-10, Vol.52 (41), p.10784-10787
Main Authors: Díaz-Moscoso, Alejandro, Tizzard, Graham J., Coles, Simon J., Cammidge, Andrew N.
Format: Article
Language:English
Subjects:
dyes/pigments
heterocycles
Hybrid structures
Macrocyclic compounds
macrocyles
organic synthesis
porphyrinoids
Porphyrins
Scaffolds
Synthesis
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Summary:Up to now, hybrid structures that lie between the ubiquitous phthalocyanine and porphyrin scaffolds have been extremely difficult to prepare. A straightforward, high‐yielding synthesis of meso‐derivatized tetrabenzotriazaporphyrins (see scheme) is described, thus unlocking access to this underdeveloped class of materials.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201306151