The Chameleonic Nature of Diazaperopyrenium Recognition Processes

Two for the price of one! The diazaperopyrenium dication behaves dichotomously in a homo‐ and heterophilic manner, allowing for complexation with itself and a variety of π‐electron‐rich donors. This chameleonic characteristic, in addition to its electronic properties, leads to self‐assembled nanowir...

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Published in:Angewandte Chemie International Edition 2012-11, Vol.51 (47), p.11872-11877
Main Authors: Basuray, Ashish N., Jacquot de Rouville, Henri-Pierre, Hartlieb, Karel J., Kikuchi, Takashi, Strutt, Nathan L., Bruns, Carson J., Ambrogio, Michael W., Avestro, Alyssa-Jennifer, Schneebeli, Severin T., Fahrenbach, Albert C., Stoddart, J. Fraser
Format: Article
Language:English
Subjects:
Complexation
Crown ethers
Donors (electronic)
Electronic properties
Nanowires
noncovalent interactions
perylene
Pictures
Recognition
rotaxanes
self-assembly
Solid state
supramolecular chemistry
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cited_by cdi_FETCH-LOGICAL-c4449-70128ed5f92a26aa1942d56e80dab3ba679785e6ec4d114be2d7cf1b298dea183
cites cdi_FETCH-LOGICAL-c4449-70128ed5f92a26aa1942d56e80dab3ba679785e6ec4d114be2d7cf1b298dea183
container_end_page 11877
container_issue 47
container_start_page 11872
container_title Angewandte Chemie International Edition
container_volume 51
creator Basuray, Ashish N.
Jacquot de Rouville, Henri-Pierre
Hartlieb, Karel J.
Kikuchi, Takashi
Strutt, Nathan L.
Bruns, Carson J.
Ambrogio, Michael W.
Avestro, Alyssa-Jennifer
Schneebeli, Severin T.
Fahrenbach, Albert C.
Stoddart, J. Fraser
description Two for the price of one! The diazaperopyrenium dication behaves dichotomously in a homo‐ and heterophilic manner, allowing for complexation with itself and a variety of π‐electron‐rich donors. This chameleonic characteristic, in addition to its electronic properties, leads to self‐assembled nanowires in the solid state, as well as to its acting as a template for aromatic crown ethers to form a [3]‐ and two [2]rotaxanes (see picture).
doi_str_mv 10.1002/anie.201205089
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source Wiley-Blackwell Read & Publish Collection
subjects Complexation
Crown ethers
Donors (electronic)
Electronic properties
Nanowires
noncovalent interactions
perylene
Pictures
Recognition
rotaxanes
self-assembly
Solid state
supramolecular chemistry
title The Chameleonic Nature of Diazaperopyrenium Recognition Processes
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