Effect of polymer infiltration on structure and properties of carbon nanotube yarns

Polymer-infiltrated carbon nanotube yarns (CNTYs) were prepared to enhance the mechanical and electrical properties of CNTYs through physical interactions. This work additionally explored the role of the polymer in altering the structures of the CNTYs. The reticulate structures of the CNTYs produced...

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Bibliographic Details
Published in:Carbon (New York) 2015-07, Vol.88, p.60-69
Main Authors: Jung, Yeonsu, Kim, Taehoon, Park, Chong Rae
Format: Article
Language:English
Subjects:
Addition polymerization
Bundling
Carbon nanotubes
Electrical properties
Infiltration
Polystyrene resins
Polyvinyl alcohols
Strength
Yarns
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Summary:Polymer-infiltrated carbon nanotube yarns (CNTYs) were prepared to enhance the mechanical and electrical properties of CNTYs through physical interactions. This work additionally explored the role of the polymer in altering the structures of the CNTYs. The reticulate structures of the CNTYs produced through aerogel methods were infiltrated with a dilute (0.05wt%) solution of polystyrene (PS), polyacrylonitrile (PAN), or polyvinyl alcohol (PVA), and the structures were characterized. The performances of the CNTYs were closely related to the junction strength and the bundle size in the reticulate CNTYs. Among the three polymers examined, infiltration of PVA—the polymer with the poorest affinity toward CNTs—yielded the greatest improvement in the mechanical and electrical properties of the CNTY. The CNTY deformation properties at each stage of the stress–strain curves could be explained based on the effects of the polymer infiltration on the structure and properties of the CNTY. The results indicated that the specific stiffness, specific strength, toughness, and electrical conductivity are significantly influenced by the molecular-level coupling between the polymer, the CNTs, and the internal structure of the CNTY.
ISSN:0008-6223
1873-3891
DOI:10.1016/j.carbon.2015.02.065