Solvent- and Achiral-Guest-Triggered Chiral Inversion in a Planar Chiral pseudo[1]Catenane

On the flipside: A planar chiral pseudo‐ [1]catenane based on pillar[5]arene, in which an alkyl chain is connected to one pillar[5]arene unit, has been synthesized. Capture and release of achiral guests and solvents trigger the inclusion and de‐threading of the alkyl chain, which causes the inversio...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-07, Vol.52 (31), p.8111-8115
Main Authors: Ogoshi, Tomoki, Akutsu, Tomohiro, Yamafuji, Daiki, Aoki, Takamichi, Yamagishi, Tada-aki
Format: Article
Language:English
Subjects:
Chains
Chirality
host-guest systems
Inclusions
Inversions
macrocycles
noncovalent interactions
pillararenes
Solvents
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Summary:On the flipside: A planar chiral pseudo‐ [1]catenane based on pillar[5]arene, in which an alkyl chain is connected to one pillar[5]arene unit, has been synthesized. Capture and release of achiral guests and solvents trigger the inclusion and de‐threading of the alkyl chain, which causes the inversion of planar chirality.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201302675