Resonant Photoemission Observations and DFT Study of s-d Hybridization in Catalytically Active Gold Clusters on Ceria Nanorods

Up shift: 6s–5d hybridization and the up‐shift of the 5d band to the Fermi level is demonstrated in catalytically active gold clusters on a cerium oxide nanorod support by using resonant photoemission spectroscopy and density functional theory modeling. These results help to explain the high catalyt...

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Published in:Angewandte Chemie International Edition 2013-07, Vol.52 (27), p.6936-6939
Main Authors: Zhou, Yunyun, Lawrence, Neil J., Wang, Lu, Kong, Lingmei, Wu, Tai-Sing, Liu, Jing, Gao, Yi, Brewer, Joseph R., Lawrence, Vivianna K., Sabirianov, Renat F., Soo, Yun-Liang, Zeng, Xiao Cheng, Dowben, Peter A., Mei, Wai Ning, Cheung, Chin Li
Format: Article
Language:English
Subjects:
Band theory
Carbon monoxide
Catalysis
Cerium oxide
Clusters
Density functional theory
Gold
gold catalysts
hybridization
Nanorods
resonant photoemission spectroscopy
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cited_by cdi_FETCH-LOGICAL-c4443-672bb66c22aee7f719f99127be25490b1bdeed8e8ee46b008b723723365a9e73
cites cdi_FETCH-LOGICAL-c4443-672bb66c22aee7f719f99127be25490b1bdeed8e8ee46b008b723723365a9e73
container_end_page 6939
container_issue 27
container_start_page 6936
container_title Angewandte Chemie International Edition
container_volume 52
creator Zhou, Yunyun
Lawrence, Neil J.
Wang, Lu
Kong, Lingmei
Wu, Tai-Sing
Liu, Jing
Gao, Yi
Brewer, Joseph R.
Lawrence, Vivianna K.
Sabirianov, Renat F.
Soo, Yun-Liang
Zeng, Xiao Cheng
Dowben, Peter A.
Mei, Wai Ning
Cheung, Chin Li
description Up shift: 6s–5d hybridization and the up‐shift of the 5d band to the Fermi level is demonstrated in catalytically active gold clusters on a cerium oxide nanorod support by using resonant photoemission spectroscopy and density functional theory modeling. These results help to explain the high catalytic activity of this system in CO oxidation.
doi_str_mv 10.1002/anie.201301383
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source Wiley-Blackwell Read & Publish Collection
subjects Band theory
Carbon monoxide
Catalysis
Cerium oxide
Clusters
Density functional theory
Gold
gold catalysts
hybridization
Nanorods
resonant photoemission spectroscopy
title Resonant Photoemission Observations and DFT Study of s-d Hybridization in Catalytically Active Gold Clusters on Ceria Nanorods
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