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The Supramolecular Balance for Transition-Metal Complexes: Assessment of Noncovalent Interactions in Phosphoramidite Palladium Complexes
The virtue of enantiomers: A general method has been developed for measuring the individual contributions of noncovalent interactions within transition‐metal complexes and dissecting them from electronic effects. On Pd complexes with one enantiopure and two enantiomeric phosphoramidite ligands, it w...
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Published in: | Angewandte Chemie International Edition 2013-02, Vol.52 (8), p.2350-2354 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The virtue of enantiomers: A general method has been developed for measuring the individual contributions of noncovalent interactions within transition‐metal complexes and dissecting them from electronic effects. On Pd complexes with one enantiopure and two enantiomeric phosphoramidite ligands, it was experimentally shown that modulations in extended CH–π and π–π interaction interfaces provide a ΔΔG value that is significant for stereoselection. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201208021 |