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The Macromolecular Route to Chiral Amplification
Cooperative phenomena, described by one‐dimensional statistical physical methods, are observed between the enantiomeric characteristics of monomeric materials and the polymers they produce. The effect of minute energies associated with this amplified chirality, although currently not interpretable,...
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| Published in: | Angewandte Chemie International Edition 1999-11, Vol.38 (21), p.3138-3154 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 3154 |
| container_issue | 21 |
| container_start_page | 3138 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 38 |
| creator | Green, Mark M. Park, Ji-Woong Sato, Takahiro Teramoto, Akio Lifson, Shneior Selinger, Robin L. B. Selinger, Jonathan V. |
| description | Cooperative phenomena, described by one‐dimensional statistical physical methods, are observed between the enantiomeric characteristics of monomeric materials and the polymers they produce. The effect of minute energies associated with this amplified chirality, although currently not interpretable, can be easily measured. Nonlinear relationships between enantiomeric excess or enantiomeric content and polymer properties may offer the possibility of developing chiral catalysts and chiral chromatographic materials in which the burden of large enantiomeric excess or content may be considerably alleviated. New approaches to information and sensor technology may become possible. |
| doi_str_mv | 10.1002/(SICI)1521-3773(19991102)38:21<3138::AID-ANIE3138>3.0.CO;2-C |
| format | article |
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New approaches to information and sensor technology may become possible.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/(SICI)1521-3773(19991102)38:21<3138::AID-ANIE3138>3.0.CO;2-C</identifier><identifier>PMID: 10556885</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>Amplification ; Asymmetric amplification ; Catalysis ; Catalysts ; Chirality ; Chromatography ; Helical structures ; Nonlinearity ; Polymers ; Production methods ; Sensors</subject><ispartof>Angewandte Chemie International Edition, 1999-11, Vol.38 (21), p.3138-3154</ispartof><rights>Copyright © 1999 WILEY‐VCH Verlag GmbH, Weinheim, Fed. 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New approaches to information and sensor technology may become possible.</description><subject>Amplification</subject><subject>Asymmetric amplification</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chirality</subject><subject>Chromatography</subject><subject>Helical structures</subject><subject>Nonlinearity</subject><subject>Polymers</subject><subject>Production methods</subject><subject>Sensors</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqNkF1r2zAUhsXYaLu2f2H4Mr1wqqMTW3I3BkH9mKFN6MfYzeBMUWTqza4zy2btv5-M2zAYg11JOrx6H-lh7BT4FDgXx5PbXOdHkAiIUUqcQJZlAFwcoToR8AEhrCfz_DSeL_Kz4fQRp3yql-9FrF-xve3F12E_Q4ylSmCXvfX-e2hXiqc7bBd4kqRKJXuM39276MrYtqmbytm-Mm100_Sdi7om0vdla6poXm-qsiit6crm4YC9KUzl3eHzus8-n5_d6U_x5fIi1_PL2M4CJl5x67K1kMYIBwZR8hTsCldgDKwLYW2mZtIUaylTg8oJZcAIrpTNZgkKJXGfTcbeTdv87J3vqC69dVVlHlzTewLJgQcxKQ_Rr2M0_ML71hW0acvatE8EnAanRINTGtTQoIZenBIqGmbBIlFwSi9OCYmTXpIgHerfPb-kX9Vu_Uf5KDEEvo2BX2Xlnv6C_wf7H-jtLCDiEVH6zj1uEab9QalEmdCXxQWdL66y61t9Qwn-Bhyhoaw</recordid><startdate>19991102</startdate><enddate>19991102</enddate><creator>Green, Mark M.</creator><creator>Park, Ji-Woong</creator><creator>Sato, Takahiro</creator><creator>Teramoto, Akio</creator><creator>Lifson, Shneior</creator><creator>Selinger, Robin L. 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New approaches to information and sensor technology may become possible.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><pmid>10556885</pmid><doi>10.1002/(SICI)1521-3773(19991102)38:21<3138::AID-ANIE3138>3.0.CO;2-C</doi><tpages>17</tpages></addata></record> |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 1999-11, Vol.38 (21), p.3138-3154 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1701091160 |
| source | Wiley |
| subjects | Amplification Asymmetric amplification Catalysis Catalysts Chirality Chromatography Helical structures Nonlinearity Polymers Production methods Sensors |
| title | The Macromolecular Route to Chiral Amplification |
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