Synthesis and characterization of valonea tannin resin and its interaction with palladium (II), rhodium (III) chloro complexes

► Valonea tannin and formaldehyde condensation reaction was carried to prepare TAR. ► TAR formation and interaction with PGM chloro complexes have been characterized. ► Pd (II) reduced to metallic Pd0 onto TAR. ► TAR–Rh (III) surface complex interaction has been characterized. ► TAR can be applied t...

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Bibliographic Details
Published in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2013-04, Vol.221, p.146-158
Main Authors: Can, Mustafa, Bulut, Emrah, Örnek, Ahmet, Özacar, Mahmut
Format: Article
Language:English
Subjects:
adsorbents
Adsorption
chemical engineering
condensation
formaldehyde
ions
Palladium
Polymer
Polymers
Polyphenol
Recovering
Resin
Resins
Rhodium
scanning electron microscopy
Spectroscopy
Tannin
Tannins
Valonea
wastes
X-ray diffraction
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Summary:► Valonea tannin and formaldehyde condensation reaction was carried to prepare TAR. ► TAR formation and interaction with PGM chloro complexes have been characterized. ► Pd (II) reduced to metallic Pd0 onto TAR. ► TAR–Rh (III) surface complex interaction has been characterized. ► TAR can be applied to recover PGMs efficiently and simply with low cost. Valonea tannin (TA) and formaldehyde condensation reaction was carried out under alkaline condition to prepare the valonea tannin–formaldehyde resol resin (TAR). Obtained resin was used as adsorbent for recovery of palladium (II) and rhodium (III) ions from chloride-containing solutions. This kind of recovery was very simple and useful for generating little secondary wastes. Interaction of adsorption also was investigated: Chloropalladium (II) species were reduced to Pd(0), while hydroxyl groups of TAR were oxidized during the adsorption. Proposed adsorption of the aquachlororhodium (III) species mostly takes place via ligand exchange mechanism. TAR, Rh-adsorbed TAR, and Pd-adsorbed TAR were characterized by scanning electron microscopy, energy-dispersive spectrometry, X-ray diffraction spectroscopy, and Fourier transform infrared–attenuated total reflection spectroscopy.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2013.01.043