High-Fidelity Noncovalent Synthesis of Hydrogen-Bonded Macrocyclic Assemblies

A hydrogen‐bonded cyclic tetramer is assembled with remarkably high effective molarities from a properly designed dinucleoside monomer. This self‐assembled species exhibits an impressive thermodynamic and kinetic stability and is formed with high fidelities within a broad concentration range. Fine d...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2015-06, Vol.54 (23), p.6780-6784
Main Authors: Montoro-García, Carlos, Camacho-García, Jorge, López-Pérez, Ana M., Bilbao, Nerea, Romero-Pérez, Sonia, Mayoral, María J., González-Rodríguez, David
Format: Article
Language:English
Subjects:
Assemblies
chelates
Concentration (composition)
Macrocyclic compounds
Monomers
noncovalent interactions
nucleosides
self-assembly
Solvents
Stability
supramolecular chemistry
Synthesis
Thermodynamics
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A hydrogen‐bonded cyclic tetramer is assembled with remarkably high effective molarities from a properly designed dinucleoside monomer. This self‐assembled species exhibits an impressive thermodynamic and kinetic stability and is formed with high fidelities within a broad concentration range. Fine design of a dinucleoside monomer leads to hydrogen‐bonded macrocyclic tetramer assemblies with high effective molarities and remarkable thermodynamic and kinetic stability. The behavior of these assemblies in various solvents is discussed.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201501321