Reversible CO sub(2) capture with porous polymers using the humidity swing

Several polymeric materials were prepared for reversible CO sub(2) capture. These materials contain quaternary ammonium ions and hydroxide counter ions, including polymers grafted from carbon black, crosslinked porous polymers templated by ordered colloidal crystals, and high internal phase emulsion...

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Published in:Energy & environmental science 2013-01, Vol.6 (2), p.488-493
Main Authors: He, Hongkun, Li, Wenwen, Zhong, Mingjiang, Konkolewicz, Dominik, Wu, Dingcai, Yaccato, Karin, Rappold, Tim, Sugar, Glenn, David, Nathaniel E, Matyjaszewski, Krzysztof
Format: Article
Language:English
Subjects:
Carbon capture and storage
Carbon dioxide
Crystals
Design engineering
Emulsions
Humidity
Polymers
Swing
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container_issue 2
container_start_page 488
container_title Energy & environmental science
container_volume 6
creator He, Hongkun
Li, Wenwen
Zhong, Mingjiang
Konkolewicz, Dominik
Wu, Dingcai
Yaccato, Karin
Rappold, Tim
Sugar, Glenn
David, Nathaniel E
Matyjaszewski, Krzysztof
description Several polymeric materials were prepared for reversible CO sub(2) capture. These materials contain quaternary ammonium ions and hydroxide counter ions, including polymers grafted from carbon black, crosslinked porous polymers templated by ordered colloidal crystals, and high internal phase emulsion systems. The porous polymers displayed an order of magnitude improvement in the kinetics of the absorption and desorption processes and a significant improvement in the swing sizes compared to a commercially available material with similar functional groups. This work suggests a new direction for the design of porous polymeric materials for CO sub(2) air capture.
doi_str_mv 10.1039/c2ee24139k
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source Royal Society of Chemistry
subjects Carbon capture and storage
Carbon dioxide
Crystals
Design engineering
Emulsions
Humidity
Polymers
Swing
title Reversible CO sub(2) capture with porous polymers using the humidity swing
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