Spin Transition and Structural Transformation in a Mononuclear Cobalt(II) Complex

A mononuclear compound, [CoII(pyterpy)2]­(PF6)2·2CH3OH [2; pyterpy = 4′-(4‴-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2]­(PF6)2·2CH2Cl2·CH3OH (3).

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Bibliographic Details
Published in:Inorganic chemistry 2015-08, Vol.54 (16), p.7670-7672
Main Authors: Guo, Ying, Yang, Xiu-Long, Wei, Rong-Jia, Zheng, Lan-Sun, Tao, Jun
Format: Article
Language:English
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Summary:A mononuclear compound, [CoII(pyterpy)2]­(PF6)2·2CH3OH [2; pyterpy = 4′-(4‴-pyridyl)-2,2′:6′,2″-terpyridine], shows a phase-transition-coupled, abrupt spin transition with a 9 K wide hysteresis that can transform to a spin-crossover compound, [CoII(pyterpy)2]­(PF6)2·2CH2Cl2·CH3OH (3).
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.5b01344