Efficient Electron Collection in Hybrid Polymer Solar Cells: In-Situ-Generated ZnO/Poly(3-hexylthiophene) Scaffolded by a TiO2 Nanorod Array

• Published in: The journal of physical chemistry letters 2013-06, Vol.4 (11), p.1983-1988
• Main Authors: Liao, Wen-Pin, Wu, Jih-Jen
• Format: Article
• Language: English
• Subjects: Energy Conversion and Storage; Energy and Charge Transport
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/jz400996d

A nanoarchitectural hybrid polymer solar cell, integrating the ordered and the bulk heterojunction hybrid polymer solar cells, is fabricated by infiltrating the diethylzinc/poly(3-hexylthiophene) (P3HT) solution into the interstices of the TiO2 nanorod (NR) array. An inorganic network composed of tiny ZnO nanocrystals is constructed in the in-situ-generated hybrid within the interstice of the single-crystalline TiO2 NRs. The TiO2 NR array, which possesses a longer electron lifetime and an appropriate electron-transport rate, serves not only as an electron transporter/collector extended from fluorine-doped tin oxide (FTO) electrode to sustain the efficient electron collection but also as a scaffold to hold the sufficient amount of ZnO/P3HT hybrid. The in-situ-generated ZnO/P3HT hybrid layer with superior charge separation efficiency can therefore be thickened in the presence of a TiO2 NR array for increasing the light-harvesting efficiency. A notable efficiency of 2.46% is therefore attained in the TiO2 NR–ZnO/P3HT hybrid solar cell.