In Situ Hydrothermal Synthesis, Crystal Structure, and Properties of a New Inorganic Holmium-Sulfate Coordination Polymer

A new chiral holmium-sulfate coordination polymer, {Ho 4 (OH) 4 (SO 4 ) 4 (H 2 O) 3 } n (1), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that 1 crystallizes in orthorhombic space group P2 1 2 1 2 1 and...

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Bibliographic Details
Published in:Inorganic and nano-metal chemistry 2015-01, Vol.45 (9), p.1296-1299
Main Authors: Li, Zhao-Hao, Hong, Dong-Feng, Li, Sha, Ning, Li-Na, Feng, Wen-Jing
Format: Article
Language:English
Subjects:
Chemical synthesis
Coordination polymers
Crystal structure
Diffraction
Holmium
Hydrothermal crystal growth
hydrothermal synthesis
Infrared radiation
Luminescence
luminescence property
Optical properties
Single crystals
Synthesis
Three dimensional
Three dimensional analysis
X-ray diffraction
X-rays
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Summary:A new chiral holmium-sulfate coordination polymer, {Ho 4 (OH) 4 (SO 4 ) 4 (H 2 O) 3 } n (1), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that 1 crystallizes in orthorhombic space group P2 1 2 1 2 1 and exhibits a unique three-dimensional chiral structure, in which {Ho4} building blocks are linked by SO 4 2- anions to form a high connected binodal network. Furthermore, thermal and luminescence properties of 1 are investigated in the solid state.
ISSN:1553-3174
2470-1556
1553-3182
2470-1564
DOI:10.1080/15533174.2013.862689